NONCLASSICAL KINETICS FOR ENZYMATIC REACTIONS IN TWO-DIMENSIONAL MEDIA

ADRIANA ISVORAN*, E. VILASECA**,*** , J.L. GARCÉS****, LAURA UNIPAN*****, F. MAS**, ***

*Department of Chemistry, University of the West, Timişoara, Pestalozzi 16, 300115 Timişoara, Romania, e-mail: aisvoran@cbg.uvt.ro
**Physical Chemistry Department, Barcelona University (UB), Barcelona, Catalonia, Spain
***Research Institute of Theoretical and Computational Chemistry of Barcelona University (IQTCUB), Barcelona, Catalonia, Spain
****Chemistry Department, Lleida University (UdL), Lleida, Catalonia, Spain
*****University of Agricultural Sciences of Banat Timişoara, Department of Agriculture, Timişoara, Romania

Abstract. Monte-Carlo simulations of Michaelis-Menten enzymatic reactions occurring in two-dimensional unobstructed media reveal non-classical kinetics reflected by time dependent rate coefficients. A comparison between different equations proposed to describe rate coefficient time dependence is made and the initial conditions influence is also analyzed.
Key words: enzymatic reactions, rate coefficients, two-dimensional media, anomalous diffusion.

Corresponding author’s e-mail: aisvoran@cbg.uvt.ro

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